A ladder based on paddlewheel diruthenium(II, II) rails connected by TCNQ rungs: a polymorph of the hexagonal 2-D network phase.
نویسندگان
چکیده
The slow diffusion reaction of [Ru(2)(O(2)CCF(3))(4)(THF)(2)] with TCNQ in CH(2)Cl(2)/4-chlorotoluene, respectively, leads to the formation of ladder chain composed of [Ru(2)] rails and TCNQ rungs in a 2 : 1 ratio.
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ترابرد الکترونی یک نانو ساختار نردبانی در حضور نقصهای شبکهای
The present research studied the electronic transport of an ideal infinite ladder nanostructure in the presence/absence of network defects by using Green’s function method at the tight-binding approximation. The network defects can be simulated by considering a finite ladder which is connected via two contacts to two similar infinite ladders. The results showed that the hopping energy of rungs...
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The title complex, {[Fe(II)Y(III)(CN)(4)(NO(3))(C(10)H(8)N(2))(CH(3)OH)(3)]·CH(3)OH·0.5H(2)O}(n), is built up of ladder-like chains oriented along the c axis. Each ladder consists of two strands based on alternating Fe(II) and Y(III) ions connected by cyanide bridges. Two such parallel chains are connected by additional cyanide anions (the 'rungs' of the ladder), which likewise connect Fe(II) a...
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عنوان ژورنال:
- Dalton transactions
دوره 31 شماره
صفحات -
تاریخ انتشار 2008